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P2. Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling with Racemic Allyl Halides
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P1. Allylic Chloro-Tetrahydropyridines: Kinetic Resolutions and Stereospecific Reactions of Enantiomerically Enriched Allyl Chlorides
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100. Double and triple ionization of isocyanic acid
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99. Mechanistic Studies of the Palladium-Catalyzed Desulfinative Cross-Coupling of Aryl Bromides and (Hetero)Aryl Sulfinate Salts
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98. A Modular, Enantioselective Synthesis of Resolvins D3, E1, and Hybrids
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97. Synthesis of the cyclopentane core of pepluanin A
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96. Chemo- and Regioselective Synthesis of Acyl-Cyclohexenes by a Tandem Acceptorless Dehydrogenation-[1,5]-Hydride Shift Cascade
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95. α-Amino Radicals via Photocatalytic Single-Electron Reduction of Imine Derivatives
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94. Bicyclic Lactams Derived from Serine or Cysteine and 2-Methylpropanal
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93. ¹⁸F-Trifluoromethanesulfinate Enables Direct C–H ¹⁸F-Trifluoromethylation of Native Aromatic Residues in Peptides
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92. Dearomative Photocatalytic Construction of Bridged 1,3-Diazepanes
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91. Structural Insights into Interaction Mechanisms of Alternative Piperazine-urea YEATS Domain Binders in MLLT1
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90. Iridium-Catalyzed Reductive Coupling of Grignard Reagents and Tertiary Amides.
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89. Synthesis of highly fluorinated arene complexes of [Rh(chelating phosphine)]+ cations, and their use in synthesis and catalysis
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88. ¹⁹F NMR studies on γ-butyrobetaine hydroxylase provide mechanistic insights and suggest a dual inhibition mode
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87. How formaldehyde reacts with amino acids.
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86. Characterisation of utrophin modulator SMT C1100 as a non-competitive inhibitor of firefly luciferase.
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85. Synthesis of Cyclic Alkenyl Dimethylsiloxanes from Alkynyl Benzyldimethylsilanes and Application in Polyene Synthesis
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84. Convergent Total Syntheses of (−)‐Rubriflordilactone B and (−)‐pseudo‐Rubriflordilactone B
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83. Highly enantioselective rhodium-catalyzed cross-coupling of boronic acids and racemic allyl halides.
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82. A General Route to Bicyclo[1.1.1]pentanes through Photoredox Catalysis
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81. Desymmetrization of Meso-bisphosphates via Rhodium Catalyzed Asymmetric Allylic Arylation
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80. Bicyclic Boronate VNRX-5133 Inhibits Metallo- and Serine-β-Lactamases
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79. Modular Sulfondiimine Synthesis Using a Stable Sulfinylamine Reagent
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78. Iridium-Catalyzed Aza-Spirocyclization of Indole-Tethered Amides: An Interrupted Pictet–Spengler Reaction
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77. Retooling Asymmetric Conjugate Additions for Sterically Demanding Substrates with an Iterative Data-Driven Approach
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76. Rhodium-catalysed vinyl 1,4-conjugate addition coupled with Sharpless asymmetric dihydroxylation in the synthesis of the CDE ring fragment of pectenotoxin-4
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75. Synthesis and biophysical properties of carbamate-locked nucleic acid (LNA) oligonucleotides with potential antisense applications
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74. Intramolecular Aldol Ring Closures of Cysteine Derivatives Leading to Densely Functionalised Pyroglutamates
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73. Total Synthesis of Berkeleylactone A
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72. Dehydrodieugenol B derivatives as antiparasitic agents: Synthesis and biological activity against Trypanosoma cruzi
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71. A General Copper-Catalyzed Synthesis of Ynamides from 1,2-Dichloroenamides​
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70. A halogen-bonding foldamer molecular film for selective reagentless anion sensing in water
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69. Synthesis of Enantioenriched α‐Chiral Bicyclo[1.1.1]pentane​​
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68. A chemically fuelled self-replicator
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67. Practical and scalable kinetic resolution of BINOLs mediated by a chiral counterion
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66. Dithiane-Directed Rh(III)-Catalyzed Amidation of Unactivated C(sp3)-H Bonds
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65. The fluorination of C–H bonds: developments and perspectives​
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64. Primary α-Tertiary Amine Synthesis via α-C–H Functionalization
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63. Anion recognition in water by charge-neutral halogen and chalcogen bonding foldamer receptors​
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62. Chemical Probes​
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61. Hydrogen Bonding Phase-Transfer Catalysis with Potassium Fluoride: Enantioselective Synthesis of β-Fluoroamines
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60. Conformational Effects on Physical-Organic Descriptors – the Case of Sterimol Steric Parameters​
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59. Hydrogen bond enabled dynamic kinetic resolution of axially chiral amides mediated by a chiral counterion
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58. Chemical epigenetics: the impact of chemical‐ and chemical biology techniques on bromodomain target validation​
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57. Desymmetrization of meso-bisphosphates using copper catalysis and alkylzirconocene nucleophiles
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56. Data-mining the diaryl(thio)urea conformational landscape: Understanding the contrasting behavior of ureas and thioureas with quantum chemistry
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55. Non‐Hydrolytic β‐Lactam Antibiotic Fragmentation by L,D‐Transpeptidases and Serine β‐Lactamase Cysteine Variants
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54. Enantioselective rhodium-catalysed insertion of trifluorodiazoethanes into tin hydrides
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53. Design, Synthesis and Characterization of Covalent KDM5 Inhibitors
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52. A structure-based approach towards identification of inhibitory fragments for eleven-nineteen-leukemia protein (ENL)
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51. Target Identification Using Chemical Probes​
Moustakim, M., Ling Felce, S., Zaarour, N., Farnie, G., McCann, F. E. and Brennan, P. E.
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50. Stereospecific 1,3-H Transfer of Indenols Proceeds via Persistent Ion-Pairs Anchored By NH···Pi Interactions
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49. Copper-catalysed synthesis of alkylidene 2-pyrrolinone derivatives from the combination of α-keto amides and alkynes
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48. Discovery of an MLLT1/3 YEATS Domain Chemical Probe
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47. Enantioselective Silver-Catalyzed Cascade Synthesis of Fused Lactone and Lactam Oxazolines
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46. Post-translational site-selective protein backbone α-deuteration
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45. Principles and Applications of Fragment-based Drug Discovery for Chemical Probes
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44. Bifunctional Iminophosphorane Catalysed Enantioselective Sulfa-Michael Addition of Alkyl Thiols to Alkenyl Benzimidazoles
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43. Photocatalytic Reverse Polarity Povarov Reaction
Leitch, J. A., Fuentes de Arriba, A. L., Tan, J., Hoff, O., Martínez, C. M. and Dixon, D. J.
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42. Polyyne formation via skeletal rearrangement induced by atomic manipulation
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41. A Bench-Stable Transfer Reagent for the Synthesis of Trifluoromethyl-sulfonimidamides from Sulfinamides
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40. A transient self-assembling self-replicator
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39. The Plant Cysteine Oxidases from Arabidopsis thaliana are kinetically tailored to act as oxygen sensors
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38. Roles of 2-oxoglutarate oxygenases and isopenicillin N synthase in β-lactam biosynthesis
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37. Synthesis and Applications of Highly Functionalized 1-Halo-3-Substituted Bicyclo[1.1.1]pentanes
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36. Rh(DPEPhos)-Catalyzed Alkyne Hydroacylation using β-Carbonyl Substituted Aldehydes. Mechanistic Insight Leads to Low Catalyst Loadings that Enables Selective Catalysis on Gram-Scale
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35. BET bromodomain ligands: Probing the WPF shelf to improve BRD4 bromodomain affinity and metabolic stability
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34. Asymmetric nucleophilic fluorination under hydrogen bonding phase-transfer catalysis
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33. An enamine controlling group for rhodium-catalyzed intermolecular hydroacylation
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32. Discovery of a novel allosteric inhibitor scaffold for polyadenosine-diphosphate-ribose polymerase 14 (PARP14) macrodomain 2
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31. Molecular machines for catalysis
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30. Structure activity relationship studies on rhodanines and derived enethiol inhibitors of metallo-β-lactamases
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29. Spironaphthoxazine switchable dyes for biological imaging
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28. Formation of quaternary centres by copper catalysed asymmetric conjugate addition to β-substituted cyclopentenones with the aid of a quantitative structure–selectivity relationship
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27. Synthesis of Polyynes Using Dicobalt Masking Groups
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26. Detecting Mechanochemical Atropisomerization within an STM Break Junction
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25. Total synthesis of (−)-himalensine A
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24. Hexafluoroisopropanol as a highly versatile solvent
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23. One-pot, Three-Component Sulfonimidamide Synthesis exploiting the Sulfinylamine Reagent N-Sulfinyltritylamine, TrNSO
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22. Copper-Catalyzed Synthesis and Applications of Yndiamide
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21. Enantioselective Conjugate Addition Catalyzed by a Copper Phosphoramidite Complex: Computational and Experimental Exploration of Asymmetric Induction
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20. Crotonases - Nature's Exceedingly Convertible Catalysts
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19. Exploiting Carbonyl Groups to Control Intermolecular Rhodium-Catalyzed Alkene and Alkyne Hydroacylation
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18. Visible light photocatalysis of 6π heterocyclization
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17. Unexpected Interactions between Alkyl Straps and Pyridine Ligands in Sulfur-Strapped Porphyrin Nanorings
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16. Potential for minimal self-replicating systems in a dynamic combinatorial library of equilibrating imines
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15. Transmission of chirality through space and across length scales
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14. Structural and stereoelectronic insights into oxygenase-catalyzed formation of ethylene from 2-oxoglutarate
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13. Neutral iodotriazole foldamers as tetradentate halogen bonding anion receptors
Borissov, A., Lim, J. Y. C., Brown, A., Christensen, K. E., Thompson, A. L., Smith, M. D. and Beer, P. D.
Chem. Commun. 2017, 53, 2483.

12. Discovery of a PCAF Bromodomain Chemical Probe
Moustakim, M., Clark, P. G. K., Trulli, L., Fuentes de Arriba, A. L., Ehebauer, M. T., Chaikuad, A., Murphy, E. J., Mendez-Johnson, J., Daniels, D., Hou, C.-F. D., Lin, Y.-H., Walker, J. R., Hui, R., Yang, H., Dorrel, L., Rogers, C. M., Monteiro, O. P., Fedorov, O., Huber, K. V. M., Knapp, S., Heer, J., Dixon, D. J., Brennan, P. E.
Angew. Chem. Int. Ed. 2017, 56, 827. DOI: 10.1002/anie.201610816.

11. Umpolung synthesis of branched α-functionalized amines from imines via photocatalytic three-component reductive coupling reactions
Fuentes de Arriba, A. L., Urbitsch, F., Dixon, D. J.
Chem. Commun. 2016, 52, 14434.

10. A Cascade Strategy Enables a Total Synthesis of (+/-)-Morphine
Chu, S., Münster, N., Balan, T., Smith. M. D.
Angew. Chem. Int. Ed. 2016, 55, 14306.

9. Posttranslational mutagenesis: A chemical strategy for exploring protein side-chain diversity
Wright, T. H., Bower, B. J., Chalker, J. M., Bernardes, G. J. L., Wiewiora, R., Ng, W.-L., Raj, R., Faulkner, S., Vallée, M. R. J., Phanumartwiwath, A., Coleman, O. D., Thézénas, M.-L., Khan, M., Galan, S. R. G., Lercher, L., Schombs, M. W., Gerstberger, S., Palm-Espling, M. E., Baldwin, A. J., Kessler, B. M., Claridge, T. D. W., Mohammed, S. and Davis, B. G.
Science 2016, 354, 597.

8. Chemical Probes and Inhibitors of Bromodomains outside the BET family
Moustakim, M., Clark, P. G. K., Hay, D. A., Dixon, D. J. and Brennan, P. E.
Med. Chem. Commun. 2016, 7, 2246.

7. Photoswitchable Spiropyran Dyads for Biological Imaging
Xiong, Y., Rivera-Fuentes, P., Sezgin, E., Jentzsch, A. V., Eggeling, C. and Anderson, H. L.
Org. Lett. 2016, 8, 3666.

6. Cp₂ZrMeCl: A Reagent for Asymmetric Methyl Addition
Garrec, K. and Fletcher, S. P.
Org. Lett. 2016, 8, 3814.

5. Recent Applications in Natural Product Synthesis of Dihydrofuran and -pyran Formation by Ring-closing Alkene Metathesis
Jacques, R., Pal, R., Parker, N. A., Sear, C. E., Smith, P. W., Ribaucourt, A. and Hodgson, D. M.
Org. Biomol. Chem. 2016, 14, 5875.

4. Organocatalytic Enantioselective Desymmetrisation
Borissov, A., Davies, T. Q., Ellis, S. R., Fleming T. F., Richardson, M. S. W. and Dixon, D. J.
Chem. Soc. Rev. 2016, 45, 5474.

3. Cascade Polycyclizations in Natural Product Synthesis
Ardkhean, R., Caputo, D. F. J., Morrow, S. M., Shi H., Xiong, Y and Anderson, E. A.
Chem. Soc. Rev. 2016, 45, 1557.

2. Strategic Application and Transformation of ortho-Disubstituted Phenyl and Cyclopropyl Ketones to Expand the Scope of Hydrogen Borrowing Catalysis
Frost, J. R., Cheong, C. B., Akhtar, W. M., Caputo, D. F. J., Stevenson, N. G. and Donohoe, T. J.
J. Am. Chem. Soc. 2015, 137, 15664.

1. Active-Metal Template Synthesis of a Halogen-Bonding Rotaxane for Anion Recognition
Langton, M. J., Xiong, Y. and Beer, P. D.
Chem. Eur. J. 2015, 21, 18910.